N,N'-Bis(tri-p-tolylphosphoranylidene)benzene-1,4-diamine (PhIm), >=95% (N)

Cat No:BMSPEM-0050

Description

N,N'-Bis(tri-p-tolylphosphoranylidene)benzene-1,4-diamine, abbreviated PhIm, is a bis(iminophosphorane) compound in which two tri-p-tolylphosphoranylidene units are bridged by a p-phenylenediamine core. The strongly electron-donating phosphoranylidene imino groups make it a useful reagent in organic synthesis, including aza-Wittig-type transformations and the preparation of nitrogen-rich heterocycles. Eata Battery offers this specialty research chemical at >=95% (N) purity.

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Basic Information

Chemical Formula	C48H46N2P2
Molecular Weight	712.86
Storage Conditions	Room temperature, under argon
Purity	>=95% (N)
English Synonyms	(1,4-Phenylenediazanylylidene)bis[tris(4-methylphenyl)phosphorane] \| PhIm
Molecular Type	Small molecule
Melting Point	245 °C (dec.)
Sensitivity	Moisture sensitive
IUPAC Name	tris(4-methylphenyl)-[4-[[tris(4-methylphenyl)-λ5-phosphanylidene]amino]phenyl]imino-λ5-phosphane
InChI	1S/C48H46N2P2/c1-35-7-23-43(24-8-35)51(44-25-9-36(2)10-26-44,45-27-11-37(3)12-28-45)49-41-19-21-42(22-20-41)50-52(46-29-13-38(4)14-30-46,47-31-15-39(5)16-32-47)48-33-17-40(6)18-34-48/h7-34H,1-6H3
InChI Key	BGJWJTLJTUQIEJ-UHFFFAOYSA-N
SMILES	CC1=CC=C(C=C1)P(=NC2=CC=C(C=C2)N=P(C3=CC=C(C=C3)C)(C4=CC=C(C=C4)C)C5=CC=C(C=C5)C)(C6=CC=C(C=C6)C)C7=CC=C(C=C7)C
Isomeric SMILES	CC1=CC=C(C=C1)P(=NC2=CC=C(C=C2)N=P(C3=CC=C(C=C3)C)(C4=CC=C(C=C4)C)C5=CC=C(C=C5)C)(C6=CC=C(C=C6)C)C7=CC=C(C=C7)C
Reaxys RN	3078570
Available Package Sizes	1 g

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